Chemical and Enzymatic Triggering of 1,2-Dioxetanes. 2. Fluoride-Induced Chemiluminescence from tert-Butyldimethylsilyloxy-Substituted Dioxetanes

摘要

Thermally stable 1,2-dioxetanes bearing tert-butyldimethylsilyloxyaryl groups have been prepared. Reaction of these dioxetanes with fluoride ion at ambient temperature in Methyl cyanate and DMSO generates chemiluminescence with efficiencies up to 25%.