Molecular State Evolution after Excitation with an Ultra-Short Laser Pulse: A Quantum Analysis of NaI and NaBr Dissociation

摘要

In recent experiments Rose, Rosker and Zewail have used a femtosecond pulse to dissociate Sodium Iodide and Sodium Bromide, and a second pulse to probe the transition state by LIF. Here we show that quantum calculations, on a model system with no adjustable parameters, reproduce the principal observed features. Ultra short laser pulse; Femtosecond; Transition state; Laser induced fluorescence; Atom; Molecule; Reprints. (mjm)