New Approaches to the Synthesis of Novel Organosilanes

摘要

The objectives of this program for the period 11/1/84 - 10/31/87 were 1) to continue to extend our research on ultrasonically accelerated reaction; 2) to continue to develop the new chemistry for low temperature generated silylenes containing large groups on the silicon atom; 3) to develop routes to silylenium ions in solution and investigate their chemistry; 4) to develop the chemistry of spiropentasilane derivatives; 5) to initiate programs in the syntheses of novel silicon-chalcogenide and silicon-transition metal compounds; and, 6) to investigate the electrochemistry of functionalized organosilanes. In this report we summarize the results obtained in trying to meet these objectives. Keywords: Ultrasound, Sonochemistry, Silicon, Organosilanes, Organoselenium, Hydrosilation, Silylenes, Silacenium.