Dynamics of Polymers Adsorbed on a Surface. A Deuterium NMR View

机译：吸附在表面上的聚合物的动力学。氘核磁共振观察

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摘要

We have studied the molecular motion of block co-polymers adsorbed on silica surfaces. We find that deuterium NMR relaxation times of specifically deuterated styrene in styrene/2-vinylpyridine co-polymers can yield information on the concentration of polymer segments of the adsorbed swollen polymers. Keywords: Solvents, Stabilization, Coatings, Composites interfaces, Block copolymers, Adsorption, Reprints. (AW)

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Blum, F. D.; Sinha, B.; Schwab, F. C.;
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年度 1988
页码 p.1-6
总页数 6
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Block copolymers; Deuterium; Polymers; Styrenes; Adsorption; Coatings; Composite materials; Dynamics; Interfaces; Molecules; Motion; Relaxation; Reprints; Silicon dioxide; Solvents; Surfaces; Pyridines; Vinyl radicals;

机译：嵌段共聚物;氘;聚合物;苯乙烯;吸附;涂料;复合材料;动力学;界面;分子;运动;松弛;重印;二氧化硅;溶剂;表面;吡啶;乙烯基;

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1. SEGMENTAL DYNAMICS OF BULK AND ADSORBED POLY(METHYL ACRYLATE)-D(3) BY DEUTERIUM NMR - EFFECT OF ADSORBED AMOUNT [J] . Lin WY., Blum FD. Macromolecules . 1997,第18期

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2. A Study of Phenylalanine Side-Chain Dynamics in Surface-Adsorbed Peptides Using Solid-State Deuterium NMR and Rotamer Library Statistics [J] . Run Li, Prashant S. Emani, Jason Ash, Journal of the American Chemical Society . 2014,第32期

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3. Deuterium Magic Angle Spinning NMR Used To Study the Dynamics of Peptides Adsorbed onto Polystyrene and Functionalized Polystyrene Surfaces [J] . Nicholas R Breen, Kun Li, Gregory L. Olsen The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2011,第30期

机译：氘魔角旋转NMR用于研究吸附在聚苯乙烯和功能化聚苯乙烯表面上的肽的动力学
4. Nanostructure,local dynamics of polymers confined in layered-silicates Investigated by Deuterium NMR [C] . International Symposium on Polymer Physics(PP'2004): Preprints . 2004

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5. Use Deuterium Solid State NMR Simulations to Study Dynamics of Peptides Adsorbed onto Inorganic Surfaces. [D] . Li, Kun. 2012

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6. Deuterium Magic Angle Spinning NMR Used to Study the Dynamics of Peptides Adsorbed onto Polystyrene and Functionalized Polystyrene Surfaces [O] . Nicholas F. Breen, Kun Li, Gregory L. Olsen, -1

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7. Molecular dynamics of adsorbed polymer thin films using NMR field cycling relaxometry [O] . Ayalur-Karunakaran Santhosh Kumar 2010

机译：使用NMR场循环弛豫法吸附聚合物薄膜的分子动力学。
8. Solid-State Deuterium NMR of Acrylate Polymers [R] . Mathias, L. J., Colletti, R. F., Spiess, H. W. 1989

机译：丙烯酸酯聚合物的固态氘核磁共振

Dynamics of Polymers Adsorbed on a Surface. A Deuterium NMR View

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