Insertion of Nitriles into the Nitrogen-Chlorine Bond. Synthesis of Polyfluoro- and (Perfluoroalkyl)tetrazanes.

摘要

Both fluorinated and non-fluorinated olefins can be inserted with ease into the nitrogen-halogen bond, e.g., hexafluoropropane or ethylene into the nitrogen-halogen bond of bromo- or iodobis(trifluoromethyl)-amine or olefins into chlorobis(trifluoromethyl)amine. We reported the stepwise insertion of CF2=CFX (X = Cl, F) into the N-Cl bonds of dichloro(perfluoroalkyl)amines. Insertions of cyanogen chloride and/or trifluoroacetonitrile into nitrogen-chlorine bonds, e.g., in chlorobis(trifluoromethyl)amine. Chlorine fluoroide, Carbon-nitrogen double bond, Nitrile, Elimination tetrazane perfluoroalkyl, Highly catenated nitrogen compounds, Stable, Dense fluids, Dimers, Reprints. (jg)