Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 88. (1)Carbaboranetungsteniridium Compounds; Crystal Structure of the Complex (Wlr(mu-CC6H4Me-4)(CO)2(PEt3)2(Eta(5)-C2B9H9Me2)).

摘要

The synthesis and properties of several tungsten-iridium complexes are reported in which an icosahedral C2B9H9Me2 cage fragment is co-ordinated to the tungsten in a pentahapto manner, with the C2B9 cage also forming bonds to the iridium. Keywords: Carbaborane, Cage compounds, Metal complexes, Reprints. (AW)