Chemical and Electrochemical Studies in Ionic Liquids

摘要

Chemical and electrochemical studies were carried out in ambient temperaturechloroaluminate molten salts composed of aluminum chloride and 1-ethyl-3-methylimidazolium chloride. Simultaneous electrochemical in EPR work was performed on polypyrrole and polyfluorene in the molten salts. The chemistry and electrochemistry of a number of solutes, benzoquinone, several molybdenum dimers, and ferro/ferricyanide, were examined. Oxygen 17 NMR spectroscopy was employed to assess the behavior of oxide in the molten salts. Gutmann donor-acceptor numbers were obtained making use of electrochemical and NMR, Phosphorus 31, measurements. Ionic liquids, Ambient temperature molten salts, Electrochemistry, Chloroaluminates. (jg)