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AM1 Studies of E2 Reactions. 1. Mechanism and Leaving Group Effects.

机译：am1对E2反应的研究。 1.机制和离开集团效应。

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The mechanisms of bimolecular gas-phase elimination reactions have been studies, by use the AM1 models. Calculations are carried out for E2 reactions between a base (B) and a molecule H-CHR-CHS-X, where B is methoxide anion and X is a neutral leaving group, and where B is a neutral base and X is an onium ion. The results are compared with experiment and earlier calculations and interpretations. Keywords: Chemical reactions, Reprints. (jes)

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作者
Dewar, M. J.; Yuan, Y. C.;
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年度 1990
页码 1-9
总页数 9
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Chemical reactions; Reaction kinetics; Elimination reactions; Molecules; Neutral; Phase; Reactive gases; Reprints; Molecular orbital theory; Sterochemistry;

机译：化学反应;反应动力学;消除反应;分子;中性;相;反应气体;重印;分子轨道理论;固色化学;

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AM1 Studies of E2 Reactions. 1. Mechanism and Leaving Group Effects.

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