Higher Oxides of Carbon C8n(n=3-5): Synthesis, Characterization and X-Ray CrystalStructure, Formation of Cyclo(m)Carbon Ions C sub n(+) (n=18,24), C sub n(-) (n-18,24,30), and Higher Carbon Ions Including C60+ in Laser Desorption Fourier Transform Mass Sp

摘要

The new higher oxides of carbon 1 (C2406), 2 (C32O8), and 3 (C40O10) have beenprepared from the macrocyclic ketals 5-7 and characterized as stable colored solids. The electronic absorption spectra of the carbon oxides 1-3 differ from those of the ketals 5-7. The absorption bands of 1-3 are broader and shifted to longer wavelength. The X-ray crystal structure of oxide 1 has been determined, showing that 1 is planar, with bent diyne units. 1-lie laser desorption Fourier transform mass spectra of 1 and 2 show a remarkable case of successive losses of two CO molecules to give C18 and C24 ions, respectively, in both positive and negative modes, 1-he C30 ion formed by fragmentation of oxide 3 is considerably less stable than the smaller homologues and is only observed in the negative mode. In the positive ion spectra recorded at low desorption laser power, ions corresponding to the dimers of the cyclocarbons are observed. In addition, higher carbon ions are formed with C60+ being abundant in the spectra obtained from all three carbon oxides. The ion distributions at high laser power correlate with previous observations on the laser desorption of graphite and other carbon-rich materials. Besides a strong C60+ ion, carbon ions up to C400+ are abundant under these conditions in all spectra.