Synthesis and Structural Characterization of New High-Valent Inorganic Fluorine Compounds and their Oxidizing Properties. Volume 1.

摘要

Noble gas fluorine oxidizers of Neon, Krypton, Argon, and Xenon have been synthesized and characterized. KrF(+) and XeF(+) cations have been made with neutral organic bases. Kr-N and Kr-O bonded molecules are also synthesized and characterized. The hypervalent compounds ClFsub6(-) and XeFsub5(-) are made. The anions IFsub6O(-), TeFsub6O(2-), TeFsub7(-) and TeFsub8(2-) anions are also made. Proof that the ClFsub6(-) anion exists is also presented. The photoelectron spectra of XeFsub2, XeFsub4, and XeFsub6 are obtained using monochromatized synchrotron radiation. The synthesis and characterization of Sb(OTeFsub5)sub6(-)Etsub4N(+), and Bi(OTeFsub5)sub6(-)Etsub4N(+) salts is completed. Radiotracer experiments involving (18)F are also accomplished to show the inability to synthesize NFsub5 is due to mainly steric reasons.