Micellar Effects on the Regiochemistry of a Diels-Alder Reaction. (Reannouncementwith New Availability Information)

摘要

The Diels-Alder reaction of surfactant 1,3-diene 1 and surfactant dienophile 2under aqueous micellar conditions gave up to a 3.0:1 ratio of cycloadducts 11 and 12. the regioselectivity of the reaction was controlled by the alignment of reactants at the micelle-H2O interface.