Molecular Diodes Fabricated by a Junction Between Mixed- and Non-Mixed ValentPolymer Films

摘要

A molecular junction between thin polymer films of occupied-state(FeII(phen)3)(Naf-SO32) and half-occupied-state (mixed valent)(FeII/III(phen)3)(Naf-SO3)2.5 has been prepared. The junction exhibits current rectification and space charge limited current transients consistent with good hole injection into the occupied-state film from the mixed valent film contact. Molecular films, Molecular diode, Space charge, Hole injection, Nafion.