Direct Observation of the Simultaneous Transfer of Vibrational Energy and Chargein the (15)N sub 2 (+)(V=2) + (14)N sub 2 Reaction

摘要

In this communication, we report the use of a mass-selected flow tube, laser-induced fluorescence technique for the study of vibrationally excited ions. Using this technique, we have made measurements of the 15N2(+) +(V=2) reaction with 14N2, which show conclusive evidence for the simultaneous transfer of vibrational energy and charge in this reaction. We believe this to be the first direct observation of such a channel in charge transfer.... Charge transfer, Energy transfer, Ion-molecule, Isotope, Nitrogen.