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Symmetrically Bridged Dimeric Vanadium Nitrido Compounds. Synthesis andCharacterization of (eta-C5Me5)V(N)Cl2

机译：对称桥联二聚钒氮化合物。（η-C5me5）V（N）Cl2的合成与表征

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Reaction of trimethylsilyl azide with (eta-C5Me5)VCl23 produces a dimericvanadium nitrido compound, (eta-C5Me5)V(N)Cl2. Spectroscopic, structural, and reactivity data indicate that this compound possesses stable and symmetric V(N)V interactions in the first example of a M2N2 compound. jg.

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Haddad, T. S.; Aistars, A.; Ziller, J. W.; Doherty, N. M.;
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年度 1993
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总页数 4
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Symmetry; Chlorides; Dimers; Vanadium; Ions; Reprints; Stability; Transition metals; Spectroscopy; Methyl radicals; Synthesis; Polymers; Reactivities; Carbon; Nitrides; Nitrogen; Chemical bonds; Silicon; Chemical reactions; Molecular structure; Azides;

机译：对称性;氯化物;二聚体;钒;离子;重印;稳定性;过渡金属;光谱学;甲基;合成;聚合物;反应活性;碳;氮化物;氮;化学键;硅;化学反应;分子结构;叠氮化物;

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专利

1. Synthesis, characterization, DFT calculations, and reactivity study of a nitrido-bridged dimeric vanadium(iv) complex [J] . Dalton transactions: An international journal of inorganic chemistry . 2020,第4期

机译：氮化物桥二聚体钒（IV）复合物的合成，表征，DFT计算和反应性研究
2. Synthesis and crystal structures of the complexes [(Me2PhP)(3)Cl2Re equivalent to N-IrCl2(C5Me5)], [(Me2PhP)(3)Cl2Re equivalent to N-IrCl(COD)], [PPh4][O3Os equivalent to N-IrCl2(C5Me5)], and [PPh4][O3Os equivalent to N-IrCl(COD)] with nitrido bridge [J] . Schwarz S., Niquet E., Saez AS., Zeitschrift fur Anorganische und Allgemeine Chemie . 2003,第14期

机译：[[Me2PhP]（3）Cl2Re相当于N-IrCl2（C5Me5）]，[[Me2PhP]（3）Cl2Re相当于N-IrCl（COD）]，[PPh4] [O3Os相当于N-IrCl2（C5Me5）]和带有亚硝基桥的[PPh4] [相当于N-IrCl（COD）的O3Os]
3. Synthesis and structure of (Me2PhP)(3)Cl2Re N-ReCl4(PMe2Ph), a mixed valent dinuclear complex with a nitrido bridge between Re-V and Re-IV [German] [J] . Haug A., Strahle J. Zeitschrift fur Anorganische und Allgemeine Chemie . 1998,第6期

机译：（Me2PhP）（3）Cl2Re N-ReCl4（PMe2Ph）的合成和结构，N-ReCl4（PMe2Ph），具有在Re-V和Re-IV之间的亚硝基桥的混合价双核络合物[德语]
4. Synthesis of Symmetrical Dimeric Dicarboxylic Acid Linked Peptides on Solid Support [C] . Sheng Jiang, Zaneta Nikolovska-Coleska, Shaomeng Wang American Peptide Symposium . 2006

机译：对称二聚体二羧酸连接肽对固体载体的合成
5. Synthesis and characterization of vanadium(V) nitrido compounds: The role of ancillary ligands in determining structure and reactivity. [D] . Killeen, Kelly Ann. 1996

机译：钒（V）亚硝基化合物的合成与表征：辅助配体在确定结构和反应性中的作用。
6. Symmetrically and Unsymmetrically Bridged Methylenebis(allopurinols): Synthesis of Dimeric Potential Anti-Gout Drugs [O] . Helmut Rosemeyer, Martina Anders, Frank Seela 2007

机译：对称和不对称桥联的亚甲基双（aluropurinols）：二聚体潜在的抗痛风药的合成。
7. Symmetrically and Unsymmetrically Bridged Methylenebis(allopurinols): Synthesis of Dimeric Potential Anti-Gout Drugs [O] . Frank Seela, Martina Anders, Helmut Rosemeyer 2007

机译：对称和不对称桥联亚甲基双（别嘌呤醇）：二聚体潜在抗痛风药物的合成
8. Nature of the Bridging Nitrido Ligand, Synthesis and Reactivity ofHeterobimetallic Nitrido-Bridged Compounds [R] . Jones, C. M., Doherty, N. M. 1995

机译：桥联氮杂配体的性质，异双金属氮杂桥联化合物的合成及反应性

Symmetrically Bridged Dimeric Vanadium Nitrido Compounds. Synthesis andCharacterization of (eta-C5Me5)V(N)Cl2

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