Preparation and X-ray Structure of CP2Ti(PH2SiH2)(PMe3)

机译：Cp2Ti（pH2siH2）（pme3）的制备及X射线结构

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The synthesis and X-ray structure determination of the novel complex,CP2Ti(PH2SiH2)(PMe3), 4 is reported. The spectroscopic and structural data indicate that 4 is best described as being a hybrid between a titanium(IV)(silyl)hydride complex and a titanium(II) silane complex. Complex 4 reacts reversibly with N2 to form the bridging dinitrogen complex 5 and, in the presence of norbornene, 4 catalytically dimerizes PH2SiH2 in quantitative yield. Silane complex, Titanium.

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Spaltenstein, E.; Palma, P.; Kreutzer, K. A.; Willoughby, C. A.; Davis, W. M.;
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年度 1994
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总页数 11
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Phosphorus; Methyl radicals; Phenyl radicals; Titanium; Methyl radicals; Silanes; Synthesis; Titanium; Yield; Spectroscopy; Complex compounds; Nitrogen; Catalysis; Dimers; Transition metals; Polymerization; Organic compounds;

机译：磷;甲基;苯基;钛;甲基;硅烷;合成;钛;产率;光谱;络合物;氮;催化;二聚体;过渡金属;聚合;有机化合物;

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1. PMe3-induced CO insertion and CO deinsertion in the zwitterionic hydrocarbyl complex Co-2(CO)(4) [mu-PhC=C(H)PPh2CC(PPh2)C(O)OC(O)]: Syntheses and X-ray structures of CO2(CO)(3)(PMe3)[mu-PhC(CO)=C(H)PPh2C-C(PPh2)C(O)OC(O)] andCo(2)(CO)(3)(PMe3)[mu-Ph [J] . Bott SG, Yang K, Richmond MG Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2007,第14期

机译：两性离子烃基络合物Co-2（CO）（4）[mu-PhC = C（H）PPh2CC（PPh2）C（O）OC（O）]中的PMe3诱导的CO插入和CO反插入：合成和X射线CO2（CO）（3）（PMe3）[mu-PhC（CO）= C（H）PPh2C-C（PPh2）C（O）OC（O）]和Co（2）（CO）（3）（ PMe3）[μ-Ph
2. W2CL4(NR2)(2)(PR'(3))(2) MOLECULES .7. PREPARATION, CHARACTERIZATION, AND STRUCTURES OF W2CL4(NHR)(2)(NH2R)(2) AND W2CL4(NHR)(2)(PME3)(2) (R=SEC-BUTYL AND CYCLOHEXYL) AND P-31(H-1) NMR STUDIES OF TRANS-TO-CIS ISOMERIZATIONS OF W2CL4(NHR)(2)(PME3)(2) [J] . Cotton FA., Wong WY., Dikarev EV. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1997,第15期

机译：W2CL4（NR2）（2）（PR'（3））（2）分子.7。 W2CL4（NHR）（2）（NH2R）（2）和W2CL4（NHR）（2）（PME3）（2）的制备，表征和结构（R = SEC-丁基和环己基）和P-31（H- 1）W2CL4（NHR）（2）（PME3）（2）的跨-CIS异构体的NMR研究
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机译：钼和钨的二氮配合物与PMe3作为共配体的质子化反应。肼配合物WCI（NNH3）（PMe3）4 CI2的X射线结构

Preparation and X-ray Structure of CP2Ti(PH2SiH2)(PMe3)

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