Synthesis, Characterization and Molecular Structure of a Compound with a Ring ofGroup 13, 15 and 16 Atoms (Me3CCH2)2InP(t-Bu)2In(CH2CMe3)2SePh

摘要

The compound (Me3CCH2)2InP(t-Bu)2In(CH2CMe3)2SePh has been prepared fromequimolar quantities of (Me3CCH2)2InP(t-Bu)22 and (Me3CCH2)2InSePh2 in pentane solution, recrystallized and fully characterized. This mixed-bridge organoindium species crystallized in the centrosymmetric space group P(bar)1 (No. 2) with a gamma 10.069(2)A, b = 11.627(4)A, c = 18.452(4)A, alpha = 100.74(2)deg, Beta = 99.33(2), gamma = 103.38(2)deg, V = 2016.9(8)A(svp)3, and Z = 2. The structure was solved and refined to R = 2.51% and wR = 2.52% for those 3747 unique data with.