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Nuclear Magnetic Resonance Study of Toluene-Polyisobutylene Solutions. 2. Vrentas-Duda Theory

机译:甲苯 - 聚异丁烯溶液的核磁共振研究。 2. Vrentas-Duda理论

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The self-diffusion coefficients of toluene in polyisobutylene have been analyzedusing the Vrentas-Duda free volume diffusion model. The diffusion coefficients were determined at different temperatures and concentrations, using the pulsed field gradient nuclear magnetic resonance technique. The data were satisfactorily described by the model and the size of the polymer jumping unit was extracted. Comparisons were made with the Fujita free volume theory and the Fujita free

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