Study of Fullerene Epoxide Electroreduction and Electropolymerization Processes

摘要

The electrochemical behaviour of C(60)0 at gold electrode in o-dichlorobenzene,dichloromethane, and a mixture of toluene and acetonitrile was studied in the potential range from 0.4-1.5 V. Three one-electron transfer steps are observed for C(60)O within this potential window. The first and the third electron transfers are attributed to the reduction of the fullerene cage. The product of