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Non-Stokes drag coefficient in single-particle electrophoresis: New insights on a classical problem

机器翻译Non-stokes drag coefficient in single-particle electrophoresis: New insights on a classical problem

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【摘要】We measured the intrinsic electrophoretic drag coefficient of a single charged particle by optically trapping the particle and applying an AC electric field, and found it to be markedly different from that of the Stokes drag. The drag coefficient, along with the measured electrical force, yield a mobility-zeta potential relation that agrees with the literature. By using the measured mobility as input, numerical calculations based on the Poisson–Nernst–Planck equations, coupled to the Navier–Stokes equation, reveal an intriguing microscopic electroosmotic flow near the particle surface, with a well-defined transition between an inner flow field and an outer flow field in the vicinity of electric double layer’s outer boundary. This distinctive interface delineates the surface that gives the correct drag coefficient and the effective electric charge. The consistency between experiments and theoretical predictions provides new insights into the classic electrophoresis problem, and can shed light on new applications of electrophoresis to investigate biological nanoparticles.

【作者】Liao, Maijia (廖麦嘉); Wei, Ming-Tzo (魏名佐); Xu, Shi-Xin (徐士鑫); Ou-Yang, H Daniel (歐陽新喬); Sheng, Ping (沈平);

【作者单位】

【年(卷),期】2019,,

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【总页数】35

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【网站名称】香港科技大学图书馆

【栏目名称】所有文件

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