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Fragmentation of multiply charged simple metal clusters in the liquid-drop stabilized jellium model

机译:液滴稳定的胶体模型中多电荷简单金属簇的碎裂

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In this work, we have used the liquid-drop model in the context of stabilized jellium model, to study the stability of Z-ply charged (Z = 1, 2, 3, 4) metal clusters of different species against fragmentation. The liquid drop energy coefficients for each r(s) value are obtained from fitting of the self-consistent Kohn-Sham results for 0 less than or equal to N less than or equal to 100. The fission barriers are calculated using the two-sphere model. Results show that the singly ionized clusters are stable against any spontaneous fragmentation. However, multiply charged clusters of sufficiently small sizes may undergo spontaneous decay via fission processes. The size at which competition between evaporation and fission starts, is predicted in good agreement with experiment for r(s) greater than or equal to 3.99. (C) 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
机译:在这项工作中,我们使用了稳定的胶体模型中的液滴模型,研究了不同物种的Z层带电(Z = 1,2,3,4)金属簇抗碎裂的稳定性。每个r(s)值的液滴能量系数是通过对0小于或等于N小于或等于100的自洽Kohn-Sham结果进行拟合获得的。使用两个球体计算裂变势垒模型。结果表明,单个离子化的簇对任何自发碎片都是稳定的。但是,足够小尺寸的多电荷簇可能会通过裂变过程而自发衰减。预测r(s)大于或等于3.99时,蒸发和裂变竞争开始的大小。 (C)2004 WILEY-VCH Verlag GmbH&Co. KGaA,Weinheim。

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