Laboratory-Scale Column Testing Using Crystalline Silicotitanate (IONSIV~(TM)IE-911)for Removing Cesium from Acidic Tank Waste Simulant.1:Cesium Exchange Capacity of a 15-cm~3Column and Dynamic Stability of the Exchange Media

摘要

Bench-scale column tests were performed using a commercial form of crystalline silicotitanate(CST)for removing radio-cesium from a surrogate acidic tank solution representative of liquid waste stored at the Idaho National Engineering and Environmental Laboratory(INEEL).An engineered form of CST ion exchanger,known as IONSIV~(TM)IE-911(UOP,Mt.Laurel,NJ,USA),was tested in 15cm~3 columns at a flow rate of 5 bed volumes per hour.These experiments showed the ion exchange material to have reasonable selectivity and capacity for removing cesium from the complex chemical matrix of the solution.However,previous testing indicated that partial neutralization of the feed stream was necessary to increase the stability of the ion exchange media.Thus,in these studies,CST degradation was determined as a function of throughput in order to better assess the stability characteristics of the exchanger for potential future waste treatment applications.Results of these tests indicate that the degradation of the CST reaches a maximum very soon after the acidic feed is introduced to the column and then rapidly declines.Total dissolution of bed material did not exceed 3% under the experimental regime used.