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Low-frequency Raman scattering of silver borate glasses

机译:硼酸银玻璃的低频拉曼散射

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The vibrational dynamics of Ag_2O-B_2O_3 glasses has been investigated by Raman spectroscopy in the frequency region below 200 cm~(-1). The spectra show the presence of the boson peak (BP), whose shape and frequency location are almost independent of the silver concentration. The increase in the sound velocity with increasing Ag+ content testifies to the progressive stiffening of the borate skeleton and refers to the existence of acoustic modes with increasing frequency. Consequently it is believed that the vibrational modes mainly contributing to the BP have a localized character and are decoupled from the acoustic phonons. An interpretation of these experimental observations ascribes a significant role in the evolution of the low-frequency vibrational dynamics of these glasses to the local vibrations of Ag~+ ions.
机译:通过拉曼光谱研究了Ag_2O-B_2O_3玻璃在200 cm〜(-1)以下的频率范围内的振动动力学。光谱表明存在玻色子峰(BP),其形状和频率位置几乎与银浓度无关。随着Ag +含量的增加,声速的增加证明了硼酸盐骨架的逐渐硬化,并且指的是随着频率增加而出现的声模。因此,可以认为,主要有助于BP的振动模式具有局部特征,并且与声子分离。对这些实验观察结果的解释归因于这些玻璃的低频振动动力学演变为Ag〜+离子局部振动的重要作用。

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