Laser flash photolysis study of the photochemical formation of colloidal Ag nanoparticles in the pressure of benzophenone

摘要

Sensitized photoreduction of Ag~+ ions and subsequent formation of colloidal Ag nanoparticles take place when an aqueous solution of a mixture of AgClO_4, sodium dodecylsulfate (SDS) and benzophenone (BP) is irradiated with near-UV light. In this study, the mechanism and kinetics of the reaction have been studied by means of nanosecond laser flash photolysis, time-resolved emission spectroscopy and also steady-state photolysis. Benzophenone ketyl radial (BPK) is formed by the hydrogen abstraction reaction of the benzophenone triplet (BPT) from SDS, which reduces Ag~+ ions. It is found that the yield of colloidal Ag nanoparticle formation decreases remarkably with increasing concentration of Ag~+ ions, indicating the efficient quenching process of BPT by Ag~+ ions. Rate constants for the oxidation of BPK as well as the quenching of BPT by Ag~+ ions in SDS micellar solution are considerably larger than those expected in the bulk solution, reflecting that Ag~+ ions and BP molecules are concentrated in the SDS micelles. The rate of colloidal Ag nanoparticle formation, V_Ag, and BP photobleach, V_BP, under steady-state irradiation with near-UV light (lambda = 365 nm) were evaluated and the dependence of V_Ag and V_BP on the concentration of Ag~+ ions is interpreted quantitatively in terms of rate constants estimated by laser flash photolysis.