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Covariant van Hove function in dilute polymer solutions

机译:稀聚合物溶液中的协变van Hove函数

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A statistically covariant relation, based on a recent Brownian relativity that was able to provide a. new macromolecular scaling picture, has been obtained in order to connect the statistical features of liquid and chain molecules forming a polymer solution. A generalized van Hove distribution function turns out to extend the Gaussian statistics to correlated media and, for dilute polymer solutions with large chain unit numbers, infers the form of a Vineyard-like convolution integral for density correlations. Depending on the imposed covariance, and the link to fundamental issues in fluid statistical mechanics, this picture encourages us to investigate conformational statistics of macromolecules in terms of the surrounding liquid correlations alone, and seeking further, which general scaling principles a Brownian-like statistic may generally undergo.
机译:基于最近的布朗相关性能够提供a的统计协变关系。为了连接形成聚合物溶液的液体和链状分子的统计特征,已经获得了新的大分子缩放图。事实证明,广义的van Hove分布函数可以将高斯统计量扩展到相关的介质,并且对于具有大链单位数的稀聚合物溶液,可以推断出类似于Vineyard的卷积积分形式以进行密度相关。取决于所施加的协方差以及与流体统计力学中基本问题的联系,这张图鼓励我们仅根据周围的液体相关性来研究大分子的构象统计,并进一步寻求类似于布朗统计的统计学的一般定标原理一般都会经历。

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