Green chemical tools in organophosphorus chemistry-organophosphorus tools in green chemistry

摘要

A variety of reactions including esterifications, alkylations, additions, cycloadditions, fragmentations, and condensations were carried out under microwave MW-assisted and solventless conditions, occasionally in ionic liquids (ILs). In a few cases, MW was synergic with phase transfer catalysis or could substitute it. A variety of P(III) ligands were developed and converted to Pt(II) complexes that can be used as catalysts. Finally, phosphorylations and the Kabachnik-Fields reaction were monitored and optimized by an on-line method, in situ Fourier transform IR spectroscopy.