Novel approach to the synthesis of phosphorus sulfur organic compounds and their metal complexes

摘要

The reaction of elemental phosphorus (P-4) and sulfur with protonodonor reagents (alcohols, phenols, and thiols) has been studied in the presence of amines and complexes based on trialkyltrithiophosphites and transition metal halides. A novel approach to the synthesis of phosphorus sulfur organic compounds has been proposed on the basis of these reactions.