Catalytic disproportionation of methyltrichlorosilane by AL-MCM-41 to prepare dichlorodimethylsilane

摘要

Al-MCM-41 samples with various Si/Al ratios were prepared and then used to disproportionate methyltrichlorosilane (MTS) to produce dichlorodimethylsilane (DMCS). The catalysts were characterized by FT-IR, X-ray powder diffraction (XRD), ~(27)Al magic angle spinning nuclear magnetic resonance (~(27)Al MAS NMR), inductively coupled plasma atomic emission spectroscopy (ICP-AES), and N _2 absorption-desorption. It reveals that all samples show the hexagonal structure of MCM-41 and exhibit large BET surface areas (over 842m ~2g ~1). FT-IR spectra of pyridine adsorption demonstrates that Al-MCM-41 samples have Lewis (L) and Brnsted (B) acidic sites, and the B acidic sites are stable in the temperature ranging from 423 to 623K. The effects of aluminum content and temperature on the disproportionation reaction were also investigated. The results show that the Al-MCM-41 with the Si/Al ratio of 15:1 exhibits an excellent activity with 100% conversion of MTS and 47% selectivity of DMCS at 623K under atmospheric pressure.