A mild and efficient method for chemoselective silylation of alcohols using hexamethyldisilazane in the presence of silica chloride

Shirini F.; Zolfigol MA.; Mohammadi K.

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A mild and efficient method for chemoselective silylation of alcohols using hexamethyldisilazane in the presence of silica chloride

机译：在氯化硅存在下使用六甲基二硅氮烷进行醇化学选择性甲硅烷基化的温和有效方法

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Reaction of alcohols with hexamethyldisilazane in the presence of silica chloride provides efficiently the corresponding trimethylsilyl ethers. This system discriminates absolutely amines and thiols from alcohols. [References: 18]

机译：醇与六甲基二硅氮烷在氧化硅存在下的反应可有效提供相应的三甲基甲硅烷基醚。该系统从酒精中完全区分出胺和硫醇。 [参考：18]

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《Phosphorus, Sulfur, and Silicon and the Related Elements》 |2003年第7期|共4页
作者
Shirini F.; Zolfigol MA.; Mohammadi K.;
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正文语种 eng
中图分类非金属元素及其化合物;
关键词
Alcohol; Chemoselective; Hexamethyldisilazane; Silica chloride; Silyl ether; Synthetic methods; Trimethylsilyl ethers; Reagents; Catalysis; Agent;

机译：醇;化学选择性;六甲基二硅氮烷;氯化硅;甲硅烷基醚;合成方法;三甲基甲硅烷基醚;试剂;催化;试剂;

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1. A mild and efficient method for chemoselective silylation of alcohols using hexamethyldisilazane in the presence of silica chloride [J] . Shirini F., Zolfigol MA., Mohammadi K. Phosphorus, Sulfur, and Silicon and the Related Elements . 2003,第7期

机译：在氯化硅存在下使用六甲基二硅氮烷进行醇化学选择性甲硅烷基化的温和有效方法
2. Hexamethyldisilazane in the presence of N,N ',N '',N '''-tetramethyltetra-2,3-pyridinoporphyrazinato copper(II) is a new, mild and highly efficient reagent for silylation of alcohols and phenols [J] . Akhlaghinia B, Asadi M, Safaee E, Phosphorus, Sulfur, and Silicon and the Related Elements . 2004,第10期

机译：在N，N'，N''，N'''-四甲基四-2,3-吡啶基卟啉锌铜（II）存在下的六甲基二硅氮烷是一种新型，温和且高效的硅烷化醇和酚的试剂
3. Highly regio- and chemoselective silylation of diethyl a-hydroxyphosphonates, alcohols and phenols in the presence of solid TiCl3(OTf) as a catalyst with hexamethyldisilazane (HMDS) at room temperature in the absence of solvent [J] . Habib Firouzabadi, Nasser Iranpoor, Soghra Farahi Catalysis Communications . 2009,第11期

机译：在固态TiCl3（OTf）作为催化剂的情况下，六甲基二硅氮烷（HMDS）在室温下，在不存在溶剂的情况下，对二乙基α-羟基膦酸酯，醇和酚的高度区域选择性和化学选择性甲硅烷基化
4. Confinement and Characterization of Deep Eutectic Solvent Based on Choline Chloride:Alcohol into Nanoporous Silica for CO_2 Capture [C] . Zaitun Ghazali, Mohd Ambar Yarmo, Rizafizah Othaman Universiti Kebangsaan Malaysia, Faculty of Science and Technology Conference Postgraduate Colloquium . 2019

机译：基于胆碱氯化胆碱的深度共晶溶剂的约束与表征：醇中的CO_2捕获中的纳米多孔二氧化硅
5. Activity Coefficients of Lithium-Chloride and Potassium-Iodide in Ethyl-Alcohol by the Boiling Point Method. [D] . Mcdowell, Maynard L. 1934

机译：沸点法测定氯化锂和碘化钾在乙醇中的活度系数。
6. An Efficient and Chemoselective Method for Oximination of β-Diketones Under Mild and Heterogeneous Conditions [O] . Mohammad Ali Zolfigol 2001

机译：在轻度和非均质条件下氧化β-二酮的高效化学选择方法
7. Rapid and highly efficient trimethylsilylation of alcohols and phenols with hexamethyldisilazane (HMDS) catalysed by in situ generated I 2 using Oxone®/KI or cerium ammonium nitrate (CAN)/KI systems under mild conditions [O] . Eskandar Kolvari, Ardeshir Khazaei, Mohammad Ali Zolfigol, 2011

机译：通过在温和条件下使用Oxone®/ ki或硝酸铈/ ki系统在原位生成的I 2催化醇和酚的醇和酚用六甲基二硅氮烷（HMDS）的快速和高效的三甲基甲硅烷基化。

A mild and efficient method for chemoselective silylation of alcohols using hexamethyldisilazane in the presence of silica chloride

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