Elastic percolation of swollen polyacrylamide (PAAm)-multiwall carbon nanotubes composite

摘要

Polyacrylamide (PAAm)-multiwalled carbon nanotube (MWNT) composites were prepared via free radical cross-linking copolymerization with different amounts of MWNTs varying in the range between 0.1 and 50wt%. The mechanical properties of swollen PAAm-MWNT composites were characterized by the tensile testing technique. A small content of embedded nanotubes dramatically changes the compressive elastic modulus of the composites. Compressive elastic modulus dramatically increases up to 1wt% MWNT on increasing nanotube content, and then decreases, presenting a critical MWNT value, indicating that there is a sudden change in the material elasticity. The critical exponent, y of elasticity, below the critical MWNT content, 1wt%, is found to be 0.58, which is consistent with the suggestions of percolation in the superelastic percolation network for PAAm-MWNT composite.