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Estimating Methyl/Methylene Groups in Asphaltene and Other Fractions of Asphalt

机译:估算沥青质和其他部分沥青中的甲基/亚甲基

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摘要

Infrared is the most widely used analytical method for interpreting the structure of petroleum fractions. In this study, IR spectra of standard normal nonade-cane were used to get e for methyl and methylene groups. A linear relationship was obtained by plotting the peak intensities at 2,954, 2,926, 2,854, 1,466, and 1,376 cm~(-1) against different amounts of N-nonadecane. The R~2 obtained for most of the plots was in the range of 0.988-0.997. The Beer-Lambert's law was used for the first time to quantitatively estimate the weight percent of methylene and methyl groups present in the different fractions of asphalt.
机译:红外是用于解释石油馏分结构的最广泛使用的分析方法。在这项研究中,使用标准的普通九碳蔗糖的红外光谱获得甲基和亚甲基的e。通过绘制2,954、2,926、2,854、1,466和1,376 cm〜(-1)的峰强度对不同量的N-十八烷作图,得出线性关系。大多数曲线图的R〜2在0.988-0.997范围内。首次使用比尔-朗伯定律来定量估算沥青不同馏分中存在的亚甲基和甲基的重量百分比。

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