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Multifunctional Additives Viscosity Index Improvers, Pour Point Depressants and Dispersants for Lube Oil

机译:多功能润滑油粘度指数改进剂,降凝剂和分散剂

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摘要

In the present work, some polymeric additives based on styrene-maleic anhydride copolymer were prepared and evaluated as multifunction lube oil additives (viscosity index improvers, pour point depressants, and detergent-dispersant additives). The styrene-maleic anhydride copolymer reacted with different alcohols (dodecyl alcohol, hexadecyl alcohol, octadecyl alcohol, and docosanol) to prepare four different types of esters and aminated with different types of amines (dodecyl amine, hexadecyl amine, and octadecyl amine) to prepare another three co-polymeric additives. Structure of the prepared compounds was confirmed by I.R. spectroscopy. The molecular weights of the prepared copolymers were determined by using gel permeation chromatograph and the percentage of csterification and amination were determined by ~1HNMR. The efficiencies of the prepared compounds as viscosity index improvers, pour point depressants, and detergenls-dispersants were investigated. It was found that the efficiency of the prepared compound as viscosity index improvers increases with increasing the concentration of additives in the solution and with increasing the molecular weight of prepared compounds, while the efficiency of the prepared compounds as pour point depressants increases with decreasing the concentration of the prepared polymers. On the other hand, the prepared compounds showed excellent dispersion power.
机译:在本工作中,制备了一些基于苯乙烯-马来酸酐共聚物的聚合物添加剂,并将其作为多功能润滑油添加剂(粘度指数改进剂,降凝剂和洗涤剂-分散剂添加剂)进行了评估。苯乙烯-马来酸酐共聚物与不同的醇(十二烷醇,十六烷醇,十八烷醇和十二烷醇)反应,以制备四种不同类型的酯,并与不同类型的胺(十二烷基胺,十六烷基胺和十八烷基胺)胺化另三种共聚添加剂。制备的化合物的结构由IR证实。光谱学。通过使用凝胶渗透色谱法确定所制备的共聚物的分子量,并通过〜1 HNMR确定酯化和胺化的百分比。研究了制备的化合物作为粘度指数改进剂,降凝剂和去垢剂分散剂的效率。发现制备的化合物作为粘度指数改进剂的效率随着溶液中添加剂浓度的增加和制备的化合物分子量的增加而增加,而制备的化合物作为降凝剂的效率随着浓度的降低而增加。制备的聚合物。另一方面,制备的化合物显示出优异的分散能力。

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