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首页> 外文期刊>Petroleum Science and Technology >Synthesis and Performance Evaluation of Vinyl Acetate-Maleic Anhydride Based Polymeric Additives for Lubricating Oil
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Synthesis and Performance Evaluation of Vinyl Acetate-Maleic Anhydride Based Polymeric Additives for Lubricating Oil

机译:醋酸乙烯酯-马来酸酐基聚合物添加剂的合成及性能评价

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摘要

Copolymer of vinyl acetate with maleic anhydride was synthesised and the prepared copolymer was esterified with different long chain alcohols (octyl, decyl, and dodecyl alcohol). The performance of the polymeric additives in different base oils was evaluated as viscosity modifier (VM), also called viscosity index improver and pour point depressant by standard ASTM methods. Intrinsic viscosity and viscometric molecular weight of the polymers were determined by Huggins and Mark-Houwink equation, respectively. It was found that the efficiency of the polymers as a VM increases with increasing the alkyl chain length of the used alcohol. Whereas, the efficiency as a pour point depressant increases with decreasing alkyl chain length of the used alcohol of the polymers.
机译:合成了乙酸乙烯酯与马来酸酐的共聚物,并将所制备的共聚物用不同的长链醇(辛基,癸基和十二烷醇)酯化。通过标准ASTM方法,将聚合物添加剂在不同基础油中的性能评估为粘度调节剂(VM),也称为粘度指数改进剂和降凝剂。聚合物的本征粘度和粘度分子量分别通过Huggins和Mark-Houwink方程确定。已经发现,作为VM的聚合物的效率随着所用醇的烷基链长度的增加而增加。然而,作为降凝剂的效率随着聚合物中所用醇的烷基链长度的减小而增加。

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