Chlorination of Adamantane and Its Derivatives by Carbon Tetrachloride in the Presence of Manganese-,Vanadium-,and Molybdenum-containing Catalysts

摘要

The feasibility of catalytic chlorination of adamantane and its derivatives by carbon tetrachloride in the presence of manganese-,vanadium-,and molybdenum-containing catalysts activated by nitrile ligands or alcohols was established.The optimum molar ratios of catalyst components and reactants and the optimum reaction conditions for selective syntheses of mono-,di-,and trichlorosubstituted adamantane derivatives with high yields were found.