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Conversion of Gas Condensate on Zinc-Containing Ultrasil Type High-Silica Zeolite

机译:含锌的Ultrasil型高硅沸石上气体冷凝物的转化

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摘要

The catalytic properties of zinc-modified, Ultrasil type high-silica zeolite in thermal catalytic conversion of gas condensate to produce olefins and aromatic hydrocarbons have been studied. Methods for controlling the product composition by varying zinc concentration and by steaming the modified zeolite have been proposed. It has been shown that the treatment of Zn-H-Ultrasil leads to the formation of Bronsted type weakly acidic OH group having an absorption band at 3670 cm(-1), which reduces the contribution of hydrogen redistribution reactions and enhances selectivity for lower C-2-C-4 olefins.
机译:研究了锌改性的Ultrasil型高硅沸石在气体冷凝物热催化转化生产烯烃和芳烃中的催化性能。已经提出了通过改变锌浓度和通过蒸煮改性沸石来控制产物组成的方法。研究表明,Zn-H-Ultrasil的处理导致布朗斯台德型弱酸性OH基的形成,其吸收带在3670 cm(-1)处,从而减少了氢再分布反应的贡献并提高了对较低C的选择性-2-C-4烯烃。

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