Synthesis of 1,2-difunctionalized fine chemicals through catalytic, enantioselective ring-opening reactions of epoxides

Schneider C

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Synthesis of 1,2-difunctionalized fine chemicals through catalytic, enantioselective ring-opening reactions of epoxides

机译：通过环氧化物的催化，对映选择性开环反应合成1,2-双官能化精细化学品

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摘要

This review summarizes the development of metal- and enzyme-catalyzed, enantioselective ring-opening reactions of meso-epoxides and racemic epoxides with various hetero and carbon nucleophiles towards the synthesis of highly enantiomerically enriched 1,2-difunctionalized fine chemicals.

机译：这篇综述总结了金属和酶催化，内消旋环氧化物和外消旋环氧化物与各种杂原子和碳亲核试剂的对映选择性开环反应，向高度对映体富集的1,2-双官能化精细化学品的合成。

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《Synthesis: International Journal of Methods in Synthetic Organic Chemistry》 |2006年第23期|共26页
作者
Schneider C;
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正文语种 eng
中图分类有机化学;
关键词
asymmetric synthesis; desymmetrization; enzymes; epoxides; kinetic resolution; HYDROLYTIC KINETIC RESOLUTION; ENANTIOENRICHED UNSATURATED DIOLS; ALPHA-DEPROTONATION-REARRANGEMENT; COOPERATIVE ASYMMETRIC CATALYSIS; CHIRAL LITHIUM AMIDE; BETA-AMINO ALCOHOLS; MESO-EPOXIDES; TERMINAL EPOXIDES; SALEN COMPLEXES; MICROBIOLOGICAL TRANSFORMATIONS;

机译：不对称合成;不对称化;酶;环氧化物;动力学拆分;水解动力学拆分;对映体富集的不饱和二元醇;α-去质子化-重排列;偶合不对称催化;手性锂酰胺;β-氨基醇;缩水甘油二胺醇变身;

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专利

1. Synthesis of 1,2-difunctionalized fine chemicals through catalytic, enantioselective ring-opening reactions of epoxides [J] . Schneider C Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2006,第23期

机译：通过环氧化物的催化，对映选择性开环反应合成1,2-双官能化精细化学品
2. REGIOCHEMICAL CONTROL OF THE RING OPENING OF 1,2-EPOXIDES BY MEANS OF CHELATING PROCESSES .11. RING OPENING REACTIONS OF ALIPHATIC MONO- AND DIFUNCTIONALIZED CIS AND TRANS 2,3- AND 3,4-EPOXY ESTERS [J] . Azzena F., Favero L., Pineschi M., Tetrahedron . 1995,第48期

机译：通过螯合过程手段对1,2-环氧化合物开环的区域化学控制.11。脂族和官能化CIS和反式2,3-和3,4-环氧酯的开环反应
3. Catalytic Enantioselective Ring-Opening Reaction of meso-Epoxides with ArSeH Using a (Salen)Ti(IV) Complex [J] . Minghua Yang* Ji Pei Jiangtao Sun Fang Yuan and Chengjian Zhu Letters in Organic Chemistry . 2010,第7期

机译：（Salen）Ti（IV）配合物与ArSeH介孔环氧化物的催化对映选择性开环反应
4. Enantioselective Synthesis and Separation of Terminal Epoxides and Diolsusing a Catalytic Membrane System containing Chiral Co(III) salen [C] . Sung-Dae Choi, rnGeon-Joong Kim 13th International Zeolite Conference, 13th, Jul 8-13, 2001, Montpellier, France . 2001

机译：使用含有手性Co（III）的催化膜体系对映体选择性合成和分离末端环氧化物和二醇
5. Asymmetric catalytic epoxide ring -opening reactions: Synthesis of highly enantiomerically enriched terminal aziridines, O-(2-hydroxyalkyl)oxime ethers, 1,2-aminooxy alcohols. [D] . Kim, Sang Kyun. 2006

机译：不对称催化环氧化物的开环反应：高度对映体富集的末端氮丙啶，O-（2-羟烷基）肟醚，1,2-氨基氧基醇的合成。
6. Enol Ethers as Substrates for Efficient Z- and Enantioselective Ring-Opening/Cross-Metathesis Reactions Promoted by Stereogenic-at-Mo Complexes. Utility in Chemical Synthesis and Mechanistic Attributes [O] . Miao Yu, Ismail Ibrahem, Masayuki Hasegawa, -1

机译：烯醚作为底物的高效Z-和对映选择性开环/交叉复分解反应的立体源钼配合促进。实用的化学合成和机械属性
7. Catalytic, Enantioselective Synthesis of 1,2-anti-Diols by Asymmetric Ring-Opening/Cross-Metathesis [O] . Hartung John, Grubbs Robert H. 2014

机译：不对称开环/交叉复分解催化对映选择性合成1,2-反二醇

Synthesis of 1,2-difunctionalized fine chemicals through catalytic, enantioselective ring-opening reactions of epoxides

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