A practical and highly efficient synthesis of alpha-(trimethylsilyl)-difluoroacetates

Amii H.; Uneyama K.; Kobayashi T.

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A practical and highly efficient synthesis of alpha-(trimethylsilyl)-difluoroacetates

机译：一种实用高效的α-（三甲基甲硅烷基）-二氟乙酸酯的合成方法

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An efficient method for the gram scale preparation of alpha-(trimethylsilyl)difluoroacetates is described. The key step involves Mg(0)-promoted selective C-F bond cleavage of readily available trifluoroacetates. [References: 18]

机译：描述了用于克规模制备α-（三甲基甲硅烷基）二氟乙酸酯的有效方法。关键步骤涉及Mg（0）促进容易获得的三氟乙酸酯的选择性C-F键裂解。 [参考：18]

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《Synthesis: International Journal of Methods in Synthetic Organic Chemistry》 |2000年第14期|共3页
作者
Amii H.; Uneyama K.; Kobayashi T.;
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正文语种 eng
中图分类有机化学;
关键词
Magnesium; Fluorine; Silicon; Esters; Electron transfer; 2; 2-difluoroketene silyl acetal; Electrochemical synthesis; Trifluoromethyl ketones; Acid;

机译：镁;氟;硅;酯;电子转移;2;2-二氟乙烯甲硅烷基乙缩醛;电化学合成;三氟甲基酮;酸;

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1. A practical and highly efficient synthesis of alpha-(trimethylsilyl)-difluoroacetates [J] . Amii H., Uneyama K., Kobayashi T. Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2000,第14期

机译：一种实用高效的α-（三甲基甲硅烷基）-二氟乙酸酯的合成方法
2. AN EFFICIENT SYNTHESIS OF ALPHA-(TRIMETHYLSILYL)ALLENYL KETONES [J] . Cunico RF., Nair SK. Synthetic Communications . 1996,第4期

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4. Highly Efficient Synthesis of Allenyltitanium Reagents Propargyl Alcohol Derivatives.Practical Synthesis of Homopargyl Alcohols [C] . Fang-Long Yang International symposium for Chinese organic chemists . 2000

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A practical and highly efficient synthesis of alpha-(trimethylsilyl)-difluoroacetates

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