Enantioselective Construction of Quaternary Carbon Stereocenter via Palladium-Catalyzed Asymmetric Allylic Alkylation of Lactones

Li Xiao-Hui; Wan Shi-Li; Chen Di; Liu Qing Rong; Ding Chang-Hua; Fang Ping; Hou Xue-Long

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Enantioselective Construction of Quaternary Carbon Stereocenter via Palladium-Catalyzed Asymmetric Allylic Alkylation of Lactones

机译：钯催化内酯的不对称烯丙基烷基化对映选择性构建季碳立体中心

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摘要

An efficient and practical method for the synthesis of ,-disubstituted six-membered lactones was developed. Enantioselective construction of quaternary carbon centers by utilizing Pd-catalyzed asymmetric allylic alkylation proved its feasibility.

机译：开发了一种高效，实用的合成β-双取代六元内酯的方法。利用Pd催化的不对称烯丙基烷基化反应对季碳中心进行对映选择性构建证明了其可行性。

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《Synthesis: International Journal of Methods in Synthetic Organic Chemistry 》 |2016年第10期| 共5页
作者
Li Xiao-Hui; Wan Shi-Li; Chen Di; Liu Qing Rong; Ding Chang-Hua; Fang Ping; Hou Xue-Long;
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正文语种 eng
中图分类化学 ;
关键词
palladium; allylic alkylation; asymmetric catalysis; lactones; quaternarycarbon;

机译：钯;烯丙基烷基化;不对称催化;内酯;季碳;

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1. Enantioselective Construction of Quaternary Carbon Stereocenter via Palladium-Catalyzed Asymmetric Allylic Alkylation of Lactones [J] . Li Xiao-Hui, Wan Shi-Li, Chen Di, Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2016 ,第10期

机译：钯催化内酯的不对称烯丙基烷基化对映选择性构建季碳立体中心
2. Enantioselective Construction of Acyclic Quaternary Carbon Stereocenters: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Amide Enolates [J] . Starkov Pavel, Moore Jared T., Duquette Douglas C., Journal of the American Chemical Society . 2017 ,第28期

机译：对映选择性构建无环季碳立体中心：完全取代的酰胺烯醇化物的钯催化脱羧烯丙基烷基化
3. Chiral alpha-Amino Acid/Palladium-Catalyzed Asymmetric Allylation of alpha-Branched beta-Ketoesters with Allylic Amines: Highly Enantioselective Construction of All-Carbon Quaternary Stereocenters [J] . Xu Ya-Nan, Zhu Meng-Zeng, Tian Shi-Kai The Journal of Organic Chemistry . 2019 ,第22期

机译：手性α-氨基酸/钯催化的α-支链β-酮酯的不对称烯丙基酯，具有烯胺胺：全碳季度立体中心的高度映射性构建
4. Construction of Contiguous Chiral Tertiary and Quaternary Carbon Centers via Palladium Catalyzed Regio-and Diastereo-selective Allylic Alkylation [C] . Daiji Ikeda, Nobuhiro Muraoka, Motoi Kawatsura, Symposium on Organometallic Chemistry . 2003

机译：通过钯催化的Regio-and Dia对酰胺选择性烯丙基烷基构建邻接手性三级和季碳中心的构建
5. Asymmetric synthesis of all-carbon alpha-aryl quaternary carbonyl compounds by palladium-catalyzed asymmetric allylic alkylation (Pd-AAA) and their application to the synthesis of biologically important 3,3 '-disubstituted oxindole and alpha-disubstituted quaternary beta-lactone frameworks. [D] . Asad, Md. Sharif A. 2015

机译：钯催化的不对称烯丙基烷基化反应（Pd-AAA）的全碳α-芳基季羰基化合物的不对称合成及其在生物学上重要的3,3'-二取代的羟吲哚和α-二取代的季铵β-内酯骨架的合成中。
6. Enantioselective Construction of Acyclic Quaternary Carbon Stereocenters: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully-Substituted Amide Enolates [O] . Pavel Starkov, Jared T. Moore, Douglas C. Duquette, -1

机译：非环状季碳立体中心的对映选择性构建：完全取代的酰胺烯醇化物的钯催化脱羧烯丙基烷基化
7. Construction of Vicinal Tertiary and All-Carbon Quaternary Stereocenters via Ir-Catalyzed Regio-, Diastereo-, and Enantioselective Allylic Alkylation and Applications in Sequential Pd Catalysis [O] . Liu Wen-Bo, Reeves Corey M., Virgil Scott C., 2013

机译：Ir催化的区域，非对映和对映选择性烯丙基烷基化反应构建三级和全碳四级立体立体中心及其在顺序Pd催化中的应用

Enantioselective Construction of Quaternary Carbon Stereocenter via Palladium-Catalyzed Asymmetric Allylic Alkylation of Lactones

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