A new reaction system for Horner-Wadsworth-Emmons olefination of optically active 4-hydroxy-2-oxo-alkylphosphonates and 4-hydroxy-1-chloro-2-oxo-alkylphosphonates with aliphatic aldehydes

Xu CF; Yuan CY

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A new reaction system for Horner-Wadsworth-Emmons olefination of optically active 4-hydroxy-2-oxo-alkylphosphonates and 4-hydroxy-1-chloro-2-oxo-alkylphosphonates with aliphatic aldehydes

机译：用于光学活性4-羟基-2-氧代烷基膦酸酯和4-羟基-1-氯-2-氧代烷基膦酸酯与脂肪族醛的霍纳-沃兹沃斯-埃蒙斯烯烃聚合的新反应系统

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摘要

A new and convenient reaction system is described for the synthesis of chiral beta'-hydroxy-alpha,beta-unsatuarated ketones based on the Horner-Wadsworth-Emmons olefination of optically active 4-hydroxy-2-oxo-alkylphosphonates and 4-hydroxy-1-chloro-2-oxo-alkylphosphonates with aliphatic aldehydes.

机译：描述了一种新的方便的反应系统，用于基于光学活性的4-羟基-2-氧代烷基膦酸酯和4-羟基1-氯-2-氧代烷基膦酸酯与脂族醛。

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《Synthesis: International Journal of Methods in Synthetic Organic Chemistry》 |2004年第15期|共10页
作者
Xu CF; Yuan CY;
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正文语种 eng
中图分类有机化学;
关键词
2 '-hydroxy-1; 2-unsatuarated ketones; Horner-Wadsworth-Emmons reaction; 4-hydroxy-2-oxo-alkylphosphonates; 4-hydroxy-1-chloro-2-oxo- alkylphosphonates; HYDROXY-BETA-KETOALKANEPHOSPHONATES; DIELS-ALDER REACTIONS; ENZYMATIC-SYNTHESIS; ORGANOPHOSPHORUS COMPOUNDS; ALPHA; BETA-EPOXY KETONES; REDUCTIVE TRANSFORMATION; ALCOHOLS; ETHERS; BORON; ROUTE;

机译：2'-羟基-1;2-未饱和的酮;Horner-Wadsworth-Emmons反应;4-羟基-2-氧代烷基膦酸酯;4-羟基-1-氯-2-氧代烷基膦酸酯;羟基-BETA-酮烷基芳基膦酸酯;DIELS醛反应;酶法合成;有机磷化合物;α;贝塔环氧酮;还原转化;醇;醚;硼;路线;

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1. A new reaction system for Horner-Wadsworth-Emmons olefination of optically active 4-hydroxy-2-oxo-alkylphosphonates and 4-hydroxy-1-chloro-2-oxo-alkylphosphonates with aliphatic aldehydes [J] . Xu CF, Yuan CY Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2004,第15期

机译：用于光学活性4-羟基-2-氧代烷基膦酸酯和4-羟基-1-氯-2-氧代烷基膦酸酯与脂肪族醛的霍纳-沃兹沃斯-埃蒙斯烯烃聚合的新反应系统
2. An Efficient and Facile Access to Substituted 1E,3E-Dienylphosphonates via Horner-Wadsworth-Emmons Olefination of alpha,beta-Unsaturated Aldehydes with Tetraethyl Methylenebisphosphonate [J] . Yahyaoui Marwa, Touil Soufiane, Samarat Ali Chemistry Letters . 2018,第6期

机译：通过α，β-不饱和醛烯烃的Hormer-Wadsworth-Emmons Olefination对取代的1E，3E-二烯基膦酰胺的高效和容易进入，所述α-不饱和醛与四乙基亚甲基双膦酸酯
3. Asymmetric synthesis of (R)-antofine and (R)-cryptopleurine via proline-catalyzed sequential α-aminoxylation and Horner-Wadsworth-Emmons olefination of aldehyde [J] . Cui M., Song H., Feng A., The Journal of Organic Chemistry . 2010,第20期

机译：通过脯氨酸催化醛的连续α-氨基木糖基化和霍纳-沃兹沃思-埃蒙斯烯化反应不对称合成（R）-antofine和（R）-隐氨氯嘌呤
4. HYDROGEN BOND NETWORKS FACILITATE THE CONVERSION OF ALIPHATIC ALDEHYDES IN THE CHARGED ACTIVE SITE OF S. CEREVISIAE TRANSKETOLASE [C] . Stefan Robert Marsden, Lorina Gjonaj, Stephen J. Eustace, Enzyme Engineering Conference . 2018

机译：氢键网络有助于在S.Cerevisiae Transkolase的带电活性位点中转化脂族醛
5. Part I. The total synthesis of (+)-trehazolin: Optically active spiroheptadienes as useful precursors for the synthesis of aminocyclopentitols. Part II. An inexpensive, nonbasic alternative to the Horner-Emmons olefination reaction. [D] . Ledford, Brian Edward. 1998

机译：第一部分：（+）-trehazolin的总合成：旋光螺庚二烯可用作合成氨基环戊醇的有用前体。第二部分霍纳-埃蒙斯烯化反应的廉价，非碱性替代品。
6. N-Heterocyclic Carbene-Catalyzed Asymmetric Oxidative Hetero-Diels-Alder Reactions with Simple Aliphatic Aldehydes [O] . Dr Xiaodan Zhao, Kyle E. Ruhl, Professor Tomislav Rovis -1

机译：N-杂环燃料催化的不对称氧化异质型与简单脂族醛的反应
7. Tandem-, Domino- and One-Pot Reactions Involving Wittig- and Horner-Wadsworth-Emmons Olefination [O] . Fatima Merza, Ahmed Taha, Thies Thiemann 2018

机译：涉及Wittig-和Horner-Wadsworth-Emmons Olefination的串联，多米诺和一锅反应

A new reaction system for Horner-Wadsworth-Emmons olefination of optically active 4-hydroxy-2-oxo-alkylphosphonates and 4-hydroxy-1-chloro-2-oxo-alkylphosphonates with aliphatic aldehydes

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