Guanidinium Ylide mediated aziridination from arylaldehydes: Scope and limitations in the formation of unactivated 3-arylaziridine-2-carboxylates

OdaY.; HadaK.; MiyataM.; TakahataC.; HayashiY.; TakahashiM.; YajimaN.; FujinamiM.; IshikawaT.

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Guanidinium Ylide mediated aziridination from arylaldehydes: Scope and limitations in the formation of unactivated 3-arylaziridine-2-carboxylates

机译：胍基内酯介导的芳基醛基叠氮化：未活化的3-芳基氮丙啶-2-羧酸盐形成的范围和限制

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摘要

The scope and limitations of guanidinium ylide mediated aziridinations from arylaldehydes yielding unactivated 3-arylaziridine-2-carboxylates, applicable to asymmetric synthesis, are discussed.

机译：讨论了由芳基醛产生的未活化的3-芳基氮丙啶-2-羧酸酯的芳基醛介导的啶基lide啶化的范围和局限性，适用于不对称合成。

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《Synthesis: International Journal of Methods in Synthetic Organic Chemistry》 |2014年第16期|共19页
作者
OdaY.; HadaK.; MiyataM.; TakahataC.; HayashiY.; TakahashiM.; YajimaN.; FujinamiM.; IshikawaT.;
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正文语种 eng
中图分类化学;
关键词
aldehydes; asymmetric synthesis; chiral auxiliaries; esters; ylides;

机译：醛;不对称合成;手性助剂;酯类;内酯类;

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1. Guanidinium Ylide mediated aziridination from arylaldehydes: Scope and limitations in the formation of unactivated 3-arylaziridine-2-carboxylates [J] . OdaY., HadaK., MiyataM., Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2014,第16期

机译：胍基内酯介导的芳基醛基叠氮化：未活化的3-芳基氮丙啶-2-羧酸盐形成的范围和限制
2. Practical and Highly Selective Sulfur Ylide-Mediated Asymmetric Epoxidations and Aziridinations Using a Cheap and Readily Available Chiral Sulfide: Extensive Studies To Map Out Scope, Limitations, and Rationalization of Diastereo- and Enantioselectivities [J] . Ona Illa, Mariam Namutebi, Chandreyee Saha, Journal of the American Chemical Society . 2013,第32期

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6. Practical and Highly Selective Sulfur Ylide-Mediated Asymmetric Epoxidations and Aziridinations Using a Cheap and Readily Available Chiral Sulfide: Extensive Studies To Map Out Scope, Limitations, and Rationalization of Diastereo- and Enantioselectivities [O] . Illa Soler, Ona, Namutebi, Mariam, Saha, Chandreyee, 2013

机译：实用和高度选择性的硫叶立德介导的不对称环氧化和叠氮化使用廉价和容易获得的手性硫化物：广泛的研究以画出范围，局限性和非对映和对映选择性的合理化

Guanidinium Ylide mediated aziridination from arylaldehydes: Scope and limitations in the formation of unactivated 3-arylaziridine-2-carboxylates

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