Synthesis of nitroso- and dinitroso compounds by reaction of nitrosyl benzoate and dinitrosylterephthalate with tetrasubstituted alkenes

摘要

The reaction of nitrosyl benzoate with tetrasubstituted alkenes at 0 degrees C produces monomeric C-nitroso compounds in high yields. Similarly, the reaction of dinitrosyl terephthalate with 2,3-dimethylbut-2-ene affords a monomeric dinitroso compound. Extension to other nitrosyl esters gives similar high yields.