Nucleophilic addition of alpha-metallated carbamates to planar chiral cationic eta(3)-allylmolybdenum complexes: A stereochemical study

Kocienski PJ; Christopher JA; Bell R; Otto B

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Nucleophilic addition of alpha-metallated carbamates to planar chiral cationic eta(3)-allylmolybdenum complexes: A stereochemical study

机译：α-金属化氨基甲酸酯向平面手性阳离子eta（3）-烯丙基钼配合物的亲核加成：立体化学研究

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摘要

Chiral alpha-(O-carbamoyl)alkyl- and alpha-(N-carbamoyl)alkylcopper(I) reagents derived from (-)-sparteine-mediated asymmetric lithiation of hindered carbamates react with cationic eta(3)-allylmolybdenum complexes with reaction of configuration.

机译：衍生自（-）-天冬氨酸介导的受阻氨基甲酸酯的不对称锂化的手性α-（O-氨基甲酰基）烷基-和α-（N-氨基甲酰基）烷基铜（I）试剂与阳离子eta（3）-烯丙基钼配合物反应组态。

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《Synthesis: International Journal of Methods in Synthetic Organic Chemistry 》 |2005年第1期| 共10页
作者
Kocienski PJ; Christopher JA; Bell R; Otto B;
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正文语种 eng
中图分类有机化学 ;
关键词
(-)-sparteine; nucleophilic addition; eta(3)-allylmolybdenum complexes; asymmetric deprotonation; carbamates; alpha-(O-carbamoyl)alkylcopper(I); alpha-(N-carbamoyl)alkylcopper(I); ENANTIOSELECTIVE SYNTHESIS; STEREOSPECIFIC SYNTHESIS; 7-SUBSTITUTED INDOLINES; ALKYLLITHIUM REAGENTS; DIRECTED LITHIATION; C-GLYCOSIDES; RADICALS; ANIONS;

机译：（-）-天冬氨酸;亲核加成;eta（3）-烯丙基钼配合物;不对称去质子化;氨基甲酸酯;α-（O-氨基甲酰基）烷基铜（I）;α-（N-氨基甲酰基）烷基铜（I）;对映体合成;立体异构合成;7-取代的吲哚类化合物;烷基锂试剂;直接锂化;C-糖苷;自由基;阴离子;

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1. Nucleophilic addition of alpha-metallated carbamates to planar chiral cationic eta(3)-allylmolybdenum complexes: A stereochemical study [J] . Kocienski PJ, Christopher JA, Bell R, Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2005 ,第1期

机译：α-金属化氨基甲酸酯向平面手性阳离子eta（3）-烯丙基钼配合物的亲核加成：立体化学研究
2. Synthetic applications of planar chiral cationic eta~3-allylmolybdenum complexes [J] . Philip Kocienski, Richard Bell, Elyse Bourque, Pure and Applied Chemistry . 2004 ,第3期

机译：平面手性阳离子η〜3-烯丙基钼配合物的合成应用
3. ENANTIOSELECTIVE SYNTHESIS OF PLANAR CHIRAL [CR(ETA(6)-ARENE)(CO)(3)] COMPLEXES VIA NUCLEOPHILIC ADDITION HYDRIDE ABSTRACTION - PRELIMINARY COMMUNICATION [J] . Fretzen A., Kundig EP. Helvetica chimica acta . 1997 ,第6期

机译：平面手性[CR（ETA（6）-芳烃）（CO）（3）]的对映体合成，通过亲核加氢物-初步通信完成
4. Skeletal Rearrangement and Nucleophilic Addition to the Hydrocarbyls of the closo-Ruthenacyclopentadiene Complexes Induced by Oxidation [C] . Makoto Moriya, Toshiro Takao, Hiroharu Suzuki Symposium on Organometallic Chemistry . 2003

机译：氧化诱导的氧化钌氰基碳化二烯配合物的烃类骨质重排和亲核外
5. Part I. Stereochemical studies on the addition of allylsilanes to aldehydes. Part II. Stereochemical studies on the addition of allylmetal reagents to acetals [D] . Almstead, Neil Gregory 1992

机译：第一部分：关于将烯丙基硅烷添加到醛中的立体化学研究。第二部分关于在缩醛中添加烯丙基金属试剂的立体化学研究
6. A New Reaction Motif: Homo-SN2′-Like Direct Nucleophilic Addition to Neutral η3-Allylmolybdenum Complexes. Total Synthesis of the Antimalarial (+)–Isofebrifugine [O] . Wenyong Chen, Lanny S. Liebeskind -1

机译：新的反应母题：智人 - sN2样直接亲核加成中性η3-allylmolybdenum配合。抗疟的全合成（+） - 异常山碱
7. A New Reaction Motif: “Homo-SN2′-Like” Direct Nucleophilic Addition to Neutral η3-Allylmolybdenum Complexes. Total Synthesis of the Antimalarial (+)-Isofebrifugine [O] . Wenyong Chen, Lanny S. Liebeskind 2009

机译：一种新的反应基序：“Homo-sn2'-liment”直接亲核除了中性η3-烯丙基钼配合物。总合成抗疟情况（+） - IsoFebrifugine

Nucleophilic addition of alpha-metallated carbamates to planar chiral cationic eta(3)-allylmolybdenum complexes: A stereochemical study

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