Synthesis and Characterization of Diaquatetra(3,5-dinitrobenzoato)tetrasilver(I) and Polymeric (Ethylenediaminesilver(I) Di(3,5-dinitrobenzoato)silver(I) Dihydrate)

摘要

Two new silver complexes have been synthesized, diaquatetra(3,5-dinitrobenzoato)-tetrasilver(I) (1) and polymeric (ethyknediaminesilver(I) di(3,S-dinitrobenzoato)silver(I) dihydrate) (2). These two complexes were characterized by elemental analyses and X-ray crystallographic technique. The crystal structure of (1) belongs to the monoclinic system with the space group P21/c, a = 5.685(11) A, b = 16.96(3) A, c = 19.67(4) A, at = 90.00 deg, beta = 90.00(3) deg, y = 90.00 deg, U = 1897(6) A~3, Z = 2, Dx = 1.544gem~(-3). The crystal structure of (2) belongs to the triclinic system with the space group P-l. a = 6.978(2) A, b = 12.919(5) A, c = 15.0291(5) A, a = 84.320(6) deg, /3 = 76.810(5) deg, y = 79.612(6) deg, U = 1295.2(8)~3, Z = 2,Dx = 1..