SYNTHESIS AND CHARACTERIZATION OF AMIDO AND AMIDO(MONOALKYLAMIDO)NITROSYL[TRIS(3,5-DIMETHYLPYRAZOLYL)BORATO]MOLYBDENUM COMPLEXES

摘要

The chloro-amido complex [Mo{HB(3,5-Me2C3HN2)(3)}(NO)Cl(NH2)] was prepared by treating [Mo{HB(3,5-Me2C3HN2)(3)}(NO)Cl-2] with an excess of ammonia. The monoalkylamido complexes [Mo{HB(3,5-Me2C3HN2)(3)}-(NO)(NH2)(NHR)] (R = Me, Et, Pr-(n) under bar and Bu-(n) under bar) were obtained by the reaction of [Mo{HB(3,5-Me2C3HN2)(3)}(NO)Cl(NH2)] with the appropriate primary amines. The IR and H-1 NMR spectra of the new complexes were investigated. [References: 16]