SYNTHESIS AND COMPLEXATION OF A NEW SOLUBLE MULTIDENTATE DIAMINOGLYOXIME AND ITS Ni(II) AND Pd(II) COMPLEXES

摘要

8,9-Bis(hydroxyimino)-7, 10-diazatetracosane (H_2L) has been prepared from dihexylamine and cyanogen-di-N-oxide. Transition metal complexes of H_2L with Ni(II) and Pd(II) have been synthesized with a metal-ligand ratio of 1:2. All complexes are very soluble in common organic solvents. The structures of the ligand and its complexes were investigated by elemental analyses, ~1H and ~(13)C NMR, IR, MS and UV/Vis spectral data.