Synthesis, characterization, and crystal structure of Di{bis[2-[(2- dimethylaminoethylimino)methyl]-6-methoxyphenolato]thiocyanatozinc(II)} Tetrakis(thiocyanato)zinc(II)

Wang C.-Y.

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Synthesis, characterization, and crystal structure of Di{bis[2-[(2- dimethylaminoethylimino)methyl]-6-methoxyphenolato]thiocyanatozinc(II)} Tetrakis(thiocyanato)zinc(II)

机译：二{双[2-[（2-二甲基氨基乙基亚氨基）甲基] -6-甲氧基苯酚基]硫氰酸根合锌（II）}四（硫氰酸根合）锌（II）的合成，表征和晶体结构

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摘要

A new Schiff base zinc(II) complex with the formula 2[Zn(C _(12)H_(18)N_2O_2)_2(NCS)][Zn(NCS) _4] was prepared and structurally characterized by elemental analysis, IR spectrum, and single crystal X-ray diffraction. The compound consists of two mononuclear [Zn(C_(12)H_(18)N_2O_2) _2(NCS)] complex cations, in which the Zn atom is in a trigonal-bipyramidal geometry, and one [Zn(NCS)_4] complex anion, in which the Zn atom is in a tetrahedral geometry.

机译：制备了一种新的具有2 [Zn（C _（12_H_（18）N_2O_2）_2（NCS）] [Zn（NCS）_4]的席夫碱锌（II）配合物，并通过元素分析，红外光谱进行了结构表征，以及单晶X射线衍射。该化合物由两个单核[Zn（C_（12）H_（18）N_2O_2）_2（NCS）]复杂阳离子组成，其中Zn原子呈三角形-双锥体的几何形状，和一个[Zn（NCS）_4]复杂。阴离子，其中Zn原子为四面体几何形状。

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《Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry》 |2011年第7期|共5页
作者
Wang C.-Y.;
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正文语种 eng
中图分类化学反应的机理和动力学;
关键词
crystal structure; Schiff base; synthesis; thiocyanate; zinc complex;

机译：晶体结构;席夫碱;合成;硫氰酸盐;锌配合物;

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1. Synthesis, characterization, and crystal structure of Di{bis[2-[(2- dimethylaminoethylimino)methyl]-6-methoxyphenolato]thiocyanatozinc(II)} Tetrakis(thiocyanato)zinc(II) [J] . Wang C.-Y. Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry . 2011,第6a7期

机译：二{双[2-[（2-二甲基氨基乙基亚氨基）甲基] -6-甲氧基苯酚基]硫氰酸根合锌（II）}四（硫氰酸根合）锌（II）的合成，表征和晶体结构
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Synthesis, characterization, and crystal structure of Di{bis[2-[(2- dimethylaminoethylimino)methyl]-6-methoxyphenolato]thiocyanatozinc(II)} Tetrakis(thiocyanato)zinc(II)

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