SYNTHESIS AND ELECTROCHEMICAL CHARACTERISTICS OF LANTHANIDE COMPLEXES WITH 2-NITRO-5,10,15,20-TETRAPHENYLPORPHYRIN AND ACETYLACETONATE

摘要

Four lanthanide complexes with 2-nitro-5,10,15,20-tetraphenylporphyrin and acetylacetonate were prepared and characterized by elemental analyses, IR, UV-Visible, ~1H NMR, XPS and molar conductance. The redox properties of the lutetium complex with 2-nitro-5, 10,1 5,204etraphenylporphyrin and acetylacetonate in dichloromethane were studied by cyclic voltammetry.