SYNTHESIS AND CHARACTERIZATION OF PALLADIUM DICHLORIDE COMPLEXES OF N-ALKYLPHENOTHIAZINES

摘要

Mononuclear palladium(ll) chloride - phenothiazine complexes have been prepared. The products were characterized by their elemental analyses, molar conductivity, magnetic susceptibility, and spectroscopic data. The molecular formulas of the new complexes were found to be: [Pd(LH)Cl-3].xH(2)O where L = chlorpromazine (CP) and x = 1, L = promethazine (PM) or ethopropazine (EP) and x = 0; and [Pd(TFH2)Cl-4] .H2O where TF = trifluoperazine. All complexes, except the CP complex, are diamagnetic species. Tentative structures have been proposed. [References: 24]