Synthesis and Characterization of titanium(IV), vanadium(III), chromium(III), and manganese(II) monobromoacetates and their complexes with organic bases

摘要

Bromoacetates of the composition MX_3(OOCCH_2Br), MX_2(OOCCH_2Br)_2, MX(OOCCH_2Br)_3, M(OOCCH_2Br)_4 (M=Ti), M(OOCCH_2Br)_3 (M=V,Cr),M(OOCCH_2Br)_2 (M=Mn) and their complexes of the types MX_2(OOCCH_2Br)_2.2B, M(OOCCH_2Br)_4.2B(M=Ti,V),M(OOCCH_2Br)_3.B(M=Cr) and M(OOCCH_2Br)_2.2B(M=Mn)(X=Cl,B=pyridine,quinoline,triethylamine or 2-fluoroaniline) have been synthesized and characterized on the basis of elemental analyses, infrared spectra, reflectance,molar conductance and magnetic susceptibility studies.