A NEW DIMERIC Pd(III)Pd(II) COMPLEX WITH 7,7,8,8- TETRACYANOQUINODIMETHANE (TCNQ)

N.Mincheva; L.Ballester

首页> 外文期刊>Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry >A NEW DIMERIC Pd(III)Pd(II) COMPLEX WITH 7,7,8,8- TETRACYANOQUINODIMETHANE (TCNQ)

【24h】

A NEW DIMERIC Pd(III)Pd(II) COMPLEX WITH 7,7,8,8- TETRACYANOQUINODIMETHANE (TCNQ)

机译：一种新型的具有7,7,8,8-四氟喹啉二甲醚（TCNQ）的二元Pd（III）Pd（II）络合物

获取原文

获取原文并翻译 | 示例

获取外文期刊封面封底 >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A dimeric Pd(III)Pd(II) complex with TCNQ was prepared in an aqueous basic solution of pH approx 9. This compound was characterized by elemental analyses and spectroscopic methods - IR, UV-Vis, EPR, magnetochemistry and ESCA. The results indicate that the formula of this complex is Pd_2(TCNQ)_3(OH)_2, (TCNQ=7,7,8,8-tetracyano-p-quinodimethane). The ligand TCNQ may exist in two different modes - as radical-anion TCNQ and neutral molecule TCNQ.

机译：在pH约为9的碱性水溶液中制备了具有TCNQ的二聚Pd（III）Pd（II）配合物。该化合物的特征在于元素分析和光谱方法-IR，UV-Vis，EPR，磁化学和ESCA。结果表明，该配合物的分子式为Pd_2（TCNQ）_3（OH）_2（TCNQ = 7,7,8,8-四氰基-对-喹二甲烷）。配体TCNQ可以两种不同的方式存在-自由基阴离子TCNQ和中性分子TCNQ。

著录项

来源
《Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry》 |2000年第9期|共9页
作者
N.Mincheva; L.Ballester;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词

相似文献

外文文献
中文文献
专利

1. Synthesis, Characterization and Biological Activity of Sodium Barbitone-Group-VIII Metals (viz. Ni(II), Pd(II) and Pt(II)) Complexes [J] . Fatma S. M. Hassan, Wafaa S. Kuran, Asmaa A. Ibrahim, 无机非金属材料(英文) . 2020,第001期
2. A NEW DIMERIC Pd(III)Pd(II) COMPLEX WITH 7,7,8,8- TETRACYANOQUINODIMETHANE (TCNQ) [J] . N.Mincheva, L.Ballester Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry . 2000,第9期

机译：一种新型的具有7,7,8,8-四氟喹啉二甲醚（TCNQ）的二元Pd（III）Pd（II）络合物
3. Reactivity of tungsten(V) mononuclear complexes towards Li(TCNQ) and TCNQ. Comparison of the crystal structures of [W(S2CNMe2)(4)][TCNQ] and [Mo(S2CNMe2)(4)][TCNQ]center dot MeCN (TCNQ = 7,7,8,8-tetracyanoquinodimethane) [J] . Le Stang S., Pala JS., Le Mest Y., Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 1998,第3期

机译：钨（V）单核配合物对Li（TCNQ）和TCNQ的反应活性。 [W（S2CNMe2）（4）] [TCNQ]和[Mo（S2CNMe2（4）] [TCNQ]中心点MeCN的晶体结构比较（TCNQ = 7,7,8,8-四氰基喹二甲烷）
4. SYNTHESIS OF NEW MONOMERIC PD(III) AND DIMERIC (PD(III),PD(II)) COMPLEXES WITH BIURET FORMED IN BASIC MEDIUM [J] . Mincheva N., Mitewa M., Gochev G., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry . 1997,第8期

机译：基本型中缩二脲的新单价PD（III）和二聚（PD（III），PD（II））配合物的合成
5. Electrophosphorescence of a thiocyanate-bridging dimeric cyclometalated iridium(III) complex [C] . Bihai Tong, Zhao Han Symposium on Photonics and Optoelectronics . 2012

机译：硫氰酸酯 - 桥接二聚体环晶铱（III）复合物的电磷晶
6. I. THEORETICAL STUDY OF THE THERMOELASTIC AND ELASTIC PROPERTIES OF ELASTIN MODEL COMPOUNDS. II. MODELS FOR THE TRAPPING OF CYCLIC POLY(DIMETHYLSILOXANE) (PDMS) CHAINS IN PDMS NETWORKS AND IMPLICATIONS OF BACKBONE INVERSION ON THE CONFIGURATIONAL CHARACTERISTICS OF PDMS. III. THEORETICAL STUDY OF THE METHYL PROTON NMR SPECTRUM OF POLY(ALPHA-METHYLSTYRENE). [D] . DEBOLT, LAWRENCE C. 1986

机译：I.弹性蛋白模型化合物的热弹性和弹性性质的理论研究。二。 PDMS网络中圈闭聚二甲基硅氧烷（PDMS）链的模型以及骨干反演对PDMS构造特性的影响。三，聚（甲基-苯乙烯基）甲基质子核磁共振谱的理论研究。
7. Structural Luminescent and Thermal Properties of Heteronuclear PdII–LnIII–PdII Complexes of Hexadentate N2O4 Schiff Base Ligand [O] . Barbara Miroslaw, Beata Cristóvão, Zbigniew Hnatejko 2018

机译：六齿N2O4席夫碱配体的异核PdII-LnIII-PdII配合物的结构发光和热性质
8. Disorder of the dimeric TCNQ–TCNQ unit in the crystal structure of [Ni(bpy)3]2(TCNQ–TCNQ)(TCNQ)2·6H2O (TCNQ is 7,7,8,8-tetracyanoquinodimethane) [O] . Juraj Černák, Juraj Kuchár, Michal Hegedüs 2017

机译：[Ni（bpy）3] 2（TCNQ-TCNQ）（TCNQ）2·6H2O晶体结构中二聚体TCNQ-TCNQ单元的失调（TCNQ为7,7,8,8-四氰基醌二甲烷）
9. Physical and Chemical Properties of Squarate Complexes. 2. Moessbauer Spectroscopy and Magnetic Susceptibility Studies of Several Dimeric and Trimeric Iron (III) Complexes Containing the Squarate Dianion. [R] . Wrobleski, J. T., Brown, D. B. 1979

机译：squarate Complexes的物理和化学性质。 2.含有方酸二价阴离子的几种二聚和三聚铁（III）配合物的moessbauer光谱和磁化率研究。

A NEW DIMERIC Pd(III)Pd(II) COMPLEX WITH 7,7,8,8- TETRACYANOQUINODIMETHANE (TCNQ)

摘要

著录项

相似文献

相关主题

期刊订阅