THE REACTIONS OF DICHLORO- AND DIBROMO(DIPHOSPHINE)PLATINUM(II) COMPLEXES WITH TRIPHENYLPHOSPHINE

摘要

In this study, ionic platinum(II) complexes of the general formula [Pt(L-L) (PPh(3))X]X, where L-L = dppm (Ph(2)PCH(2)PPh(2)), dppe (Ph(2)P(CH2)(2)PPh(2)), dppp (Ph(2)P(CH2)(3)PPh(2)), dcpe (Cy(2)P(CH2)(2)PCY2), CY = cyclohexyl (C6H11); X = Cl-, Br-, have been synthesized by the reaction of [Pt(L-L)X(2)] with PPh(3) and characterized by P-31(H-1)- nmr, ir, uv-visible and conductance data. [References: 17]